There are only 14 electrons, so
this structure does not obey The Eighteen Electron Rule. As drawn the C-5
ring would be C5H4 and only give 1e- (1).
This is wrong. For stability C5H4 need giving all
5e- (
5).
Fe bonds to all the carbons in the ring.
(Phosphorus has 5 valence electrons,
s2p3, but there are 3 valence electrons used by the
3 Phenyl-groups, so there are just 2 valence electrons left for the bonding
with Fe.)
Fe = 8e-
C5H4 = 1e- COT = 2e- CH3 = 1e- PPh3 = 2e- 14e- |